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( OC -6-34)-((2 S )-1-( tert -Butoxy)-4-(butylsulfonimidoyl)-1-oxobutan-2-yl)carbamato(1 R ,2 R )-1,2-cyclohexanediaminohydroxidooxalatoplatinum(IV) (4b) Ox(OH) 2 was suspended in anhy

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To interpret the binding isotope effects quantitatively, we performed ab initio calculations that were then used to calculate binding isotope effects.[75, 81] The C-H bond of a model 5-deoxypyridoxal-Ala imine was incrementally lengthened and held fixed while the geometry of the remaining atoms was optimized