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The easiness of formation of such covalent bond depends on overall redox potential of environment as well as pH (at low pH the equilibrium is shifted to the reduced, -SH form, under more basic conditions the -SH group is more willing to be oxidized and replaced by -SR, where R is anything except for hydrogen)

Lack of association of the CEP72 rs924607 TT genotype with vincristine-related peripheral neuropathy during the early phase of pediatric acute lymphoblastic leukemia treatment in a Spanish population

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Biochem Biophys Res Commun 2006

This is achieved through the intrinsic 'safety lock' mechanism encoded in the N-terminal region of the fibrinogen -chain 52 which prevents premature fibrin polymerisation in the absence of thrombin activation 53